She uses the Breath of Love (恋の呼吸 Koi no Kokyu) which is derived from the Breath of Flames (炎の呼吸 Hono no Kokyu) and her instructor was Shinjuro Rengoku the former Flame Pillar

This Breathing Style is the personal creation of Mitsuri Kanroji, made by altering the Flame Breathing she learned from Kyojuro Rengoku to suit her special composition and physiology. It takes advantage of her body's unique muscle density, which grants her inhuman strength without making her physically bulky, to deliver fast and powerful blows
Breathing Style [] Love Breathing (恋 (こい) の 呼 (こ) 吸 (きゅう) , Koi no kokyū?): A Breathing Style Mitsuri created herself based on her experience using Flame Breathing, from being the Tsuguko of Kyojuro Rengoku. Love Breathing incorporates elements of Mitsuri's superhuman flexibility and her unique whip-like Nichirin Sword
Mitsuri Kanroji uses the Love Breathing technique, which is something that she created herself that utilizes her strengths in fights, hence her placement as the Love Hashira.
Demon Slayer: What is Breath of Love and why is Mitsuri Kanroji the only user? The Breath of Love is a breathing technique that was developed by Mitsuri Kanroji herself.
The Breath of Love is a breathing technique that was developed by Mitsuri Kanroji herself. This is a breathing technique that is derived from Flame Breathing, since she trained under Kyojuro Rengoku's tutelage. VC2zC.
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  • what breathing style does mitsuri use